Insights into the mechanism for gold catalysis: behaviour of gold(I) amide complexes in solution.
نویسندگان
چکیده
We report the synthesis and activity of new mononuclear and dinuclear gold amide complexes 1-7. The dinuclear complexes 6b and 7 were characterised by single crystal X-ray analysis. We also report solution NMR and freezing point depression experiments to rationalise their behaviour in solution and question the de-ligation process invoked in gold catalysis.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 18 شماره
صفحات -
تاریخ انتشار 2013